[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2008). E64, m1326  [ doi:10.1107/S160053680803033X ]

Poly[tris([mu]3-5-aminoisophthalato)diaquadicerium(III)]

H.-J. Ma, Y.-H. Fan, Q. Wang, C.-F. Bi and D.-M. Zhang

Abstract: In the title complex, [Ce2(C8H5NO4)3(H2O)2]n, each Ce ion is in nine-coordinated environment. Eight O atoms from six ligands participate in coordination, in addition to one O atom from a water molecule. Both carboxylate groups from the ligands chelate the Ce atoms, forming two four-membered rings. The 5-aminoisophthalate ligands also bridge the Ce centers, forming a two-dimensional network, and O-H...O and N-H...O hydrogen bonds complete the structure.


Copyright © International Union of Crystallography
IUCr Webmaster