Acta Cryst. (2008). E64, m1256-m1257  [ doi:10.1107/S1600536808028298 ]

Poly[[{₃-tris[2-(4-phenyl-1,2,3-triazol-1-yl)ethyl]amine}silver(I)] hexafluoridophosphate]

H. Ohi, M. Shimizu, M. Obata, T. Funabiki and S. Yano

Abstract: The title compound, {[Ag(L)]PF₆)_n {L is tris[2-(4-phenyl-1,2,3-triazol-1-yl)ethyl]amine, C₃₀H₃₀N₁₀}, consists of alternating two-dimensional cationic layers of [Ag(L)]⁺ and anionic PF₆^- layers. Each Ag^I atom is three coordinated in a T-shaped geometry by three N atoms from three ligands. Each ligand links three Ag^I atoms, generating a two-dimensional network structure with two different metallacycles, A and B. In A, eight coordination units from four ligands connect four Ag^I atoms, forming a 48-membered ring. In B, four coordination units from two ligands link two Ag^I atoms, forming a 24-membered ring. Each B ring is surrounded by four A rings, and each A ring has four A and four B rings as neighbours. This cationic layer thus generates a 4.8² topology network, with each Ag^I centre and ligand acting as a three-connected topological node.

Online 13 September 2008

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