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Acta Cryst. (2008). E64, m1258  [ doi:10.1107/S1600536808028389 ]

catena-Poly[[(2,2'-bipyridine-[kappa]2N,N')nickel(II)]-[mu]-oxalato-[kappa]4O1,O2:O1',O2']

S. Li, X.-L. Yan, S.-B. Wang and Y.-F. Ma

Abstract: The title compound, [Ni(C2O4)(C10H8N2)]n, is isostructural with its MnII, FeII, CuII and ZnII analogues. Each NiII atom is chelated by two oxalate ligands and one 2,2'-bipyridine, forming a slightly distorted octahedral geometry. Oxlate acts as a bridge to link neighbouring pairs of NiII cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.

Online 13 September 2008


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