[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2008). E64, o1878-o1879  [ doi:10.1107/S1600536808027761 ]

4-Aminopyridinium 4-nitrobenzoate 4-nitrobenzoic acid

C. K. Quah, S. R. Jebas and H.-K. Fun

Abstract: The asymmetric unit of the title compound, C5H7N2+·C7H4NO4-·C7H5NO4, consists of an aminopyridinium cation, a 4-nitrobenzoate anion and a neutral 4-nitrobenzoic acid molecule. The pyridine ring forms dihedral angles of 64.70 (5)° and 70.37 (5)°, respectively, with the benzene rings of 4-nitrobenzoic acid and 4-nitrobenzoate. In the crystal structure, the cations, anions and the neutral 4-nitrobenzoic acid molecules are linked by O-H...O and N-H...O hydrogen bonds, forming a two-dimensional network parallel to (001). Adjacent networks are cross-linked via C-H...O hydrogen bonds and [pi]-[pi] stacking interactions [centroid-centroid distances 3.6339 (6) and 3.6566 (6) Å].

Online 6 September 2008


Copyright © International Union of Crystallography
IUCr Webmaster