Acta Cryst. (2008). E64, m1343  [ doi:10.1107/S1600536808030663 ]

Aqua(picolinato N-oxide-²O¹,O²)(pyridine-2,6-dicarboxylato-³O,N,O')iron(III) monohydrate

D. Han and D. Wang

Abstract: In the title compound, [Fe(C₆H₄NO₃)(C₇H₃NO₄)(H₂O)]·H₂O, the Fe^III ion is coordinated by two O and one N atoms from a pyridine-2,6-dicarboxylate ligand, by two O atoms from a picolinate N-oxide ligand and by one water O atom in a distorted octahedral geometry [Fe-O = 1.940 (3)-2.033 (3) Å and Fe-N = 2.057 (4) Å]. In the crystal structure, the coordinated and solvent water molecules contribute to the formation of O-HO hydrogen bonds, which link the molecules into layers parallel to the ab plane.

Online 27 September 2008

Copyright © International Union of Crystallography
IUCr Webmaster