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Acta Cryst. (2008). E64, m1293-m1294  [ doi:10.1107/S1600536808029450 ]

Tetraaquabis(2-sulfamoylbenzoato)manganese(II)

R. Akram, W. A. Siddiqui, M. N. Tahir, H. L. Siddiqui and A. Iqbal

Abstract: In the title compound, [Mn(C7H6NO4S)2(H2O)4], the Mn atom, lying on an inversion center, exhibits a distorted octahedral coordination by six O atoms, two from carboxylate groups and four from water molecules. The SO2NH2 group is involved in a three dimensional polymeric hydrogen bonding network along with the water molecules. [pi]-Stacking interactions parallel to the c axis lead to a separation of 4.0050 (12) Å between the centroids of the benzene rings.


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