Acta Cryst. (2008). E64, m1337  [ doi:10.1107/S1600536808030705 ]

(Nitrato-O)oxido(5,10,15,20-tetraphenylporphyrinato-⁴N)molybdenum(V) benzene solvate

S. M. Carter, N. Xu, M. A. Khan, D. R. Powell and G. B. Richter-Addo

Abstract: In the title compound, [Mo(C₄₄H₂₈N₄)(NO₃)O]·C₆H₆, the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo-O bond to a nitrate O atom. A centrosymmetric benzene solvent molecule is situated between adjacent porphyrin molecules.

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