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Acta Cryst. (2008). E64, m1287  [ doi:10.1107/S1600536808029279 ]

Poly[diaquabis[[mu]2-2,4-(dichlorophenoxy)acetato-[kappa]2O:O']iron(II)]

W.-B. Pan, X.-H. Xu, X.-H. Huang and R.-H. Zeng

Abstract: In the title compound, [Fe(C8H5Cl2O3)2(H2O)2]n, the FeII atom is located on an inversion center. It is coordinated by four O atoms from four 2,4-dichlorophenoxyacetate ligands and two water molecules, displaying a distorted octahedral geometry. The carboxylate groups of the 2,4-dichlorophenoxyacetate ligands link the Fe atoms, forming a polymeric layered network in the bc plane. Intralayer O-H...O hydrogen bonds enhance the stability of the two-dimensional network.

Online 20 September 2008


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