Acta Cryst. (2008). E64, m1272  [ doi:10.1107/S1600536808028857 ]

{Bis[2-(dicyclohexylphosphino)phenyl]methylsilyl-³P,Si,P'}chloridoplatinum(II)

Y.-H. Li, Y. Zhang, M.-M. Zhao and X. Li

Abstract: In the title compound, [Pt(C₃₇H₅₅P₂Si)Cl], prepared from MeSiH[(cy)₂PC₆H₄]₂ and [Pt(cod)Cl₂] (cy = cyclohexyl; cod = cycloocta-1,5-diene), the Pt^II atom is coordinated by two P atoms, one Si atom and one Cl atom in a distorted square-planar geometry. The two P atoms are in a trans arrangement and the four cyclohexane rings adopt a chair conformation.

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