Iodido(1,10-phenanthroline-κ2N,N′)(piperine-1-carbodithioato-κ2S,S′)copper(II)

Fan, L.-Q.

doi:10.1107/S1600536808028213

Volume 64
Part 10
Page m1249
October 2008

Received 30 August 2008
Accepted 3 September 2008
Online 6 September 2008

Key indicators
Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.010 Å
R = 0.063
wR = 0.166
Data-to-parameter ratio = 18.7
Details

Iodido(1,10-phenanthroline-²N,N')(piperine-1-carbodithioato-²S,S')copper(II)

Le-Qing Fan ^a ^*

^aInstitute of Materials Physical Chemistry, and Key Laboratory for Functional Materials of Fujian Higher Education, Huaqiao University, Quanzhou, Fujian 362021, People's Republic of China
Correspondence e-mail: lqfan@hqu.edu.cn

In the title compound, [Cu(C₆H₁₀NS₂)I(C₁₂H₈N₂)], the Cu^II ion is coordinated by one iodide ion, two N atoms of the phenanthroline ligand and two S atoms from the piperidyldithiocarbamate ligand in a distorted square-pyramidal environment.

Related literature

For related literature, see: Englhardt et al. (1998); Fernández et al. (2000); Koh et al. (2003); Noro et al. (2000); Yaghi et al. (1998).

Experimental

Crystal data

[Cu(C₆H₁₀NS₂)I(C₁₂H₈N₂)]
M_r = 530.91
Monoclinic, P 2₁ /c
a = 6.408 (4) Å
b = 17.11 (1) Å
c = 18.400 (9) Å
= 108.42 (2)°
V = 1914 (2) Å³
Z = 4
Mo K radiation
= 2.98 mm^-1
T = 293 (2) K
0.40 × 0.08 × 0.03 mm

Data collection

Rigaku Mercury CCD diffractometer
Absorption correction: multi-scan (CrystalClear; Rigaku,2000) T_min = 0.751, T_max = 0.915
14752 measured reflections
4236 independent reflections
3298 reflections with I > 2(I)
R_int = 0.069

Refinement

R[F² > 2(F²)] = 0.063
wR(F²) = 0.166
S = 1.09
4236 reflections
226 parameters
H-atom parameters constrained
_max = 1.41 e Å^-3
_min = -1.52 e Å^-3

Data collection: CrystalClear (Rigaku, 2000); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: IM2082 ).

Acknowledgements

This work was supported financially by the Research Fund of Huaqiao University (No. 06BS216) and the Young Talent Fund of Fujian Province (No. 2007F3060).

References

Englhardt, L. M., Healy, P. C., Shephard, R. M., Skelton, B. W. & White, A. W. (1998). Inorg. Chem. 27, 2371-2373.
Fernández, E. J., López-de-Luzuriaga, J. M., Monge, M., Olmos, E., Laguna, A., Villacampa, M. D. & Jones, P. G. (2000). J. Cluster Sci. 11, 153-166.
Koh, Y. W., Lai, C. S., Du, A. Y., Tiekink, E. R. T. & Loh, K. P. (2003). Chem. Mater. 15, 4544-4554.
Noro, S., Kitagawa, S., Kondo, M. & Seki, K. (2000). Angew. Chem. Int. Ed. 39, 2081-2084.
Rigaku (2000). CrystalClear. Rigaku Corporation, Akishima, Tokyo, Japan.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Yaghi, O. M., Li, H., David, C., Richardson, D. & Groy, T. L. (1998). Acc. Chem. Res. 31, 474-484.

metal-organic compounds

Iodido(1,10-phenanthroline-2N,N')(piperine-1-carbodithioato-2S,S')copper(II)