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Acta Cryst. (2008). E64, m1295-m1296 [ doi:10.1107/S1600536808029413 ]
3-pyridine-2,3-dicarboxylato-
4N,O2:O3:O3'] dihydrate]Abstract: In the title coordination polymer, {[Mn(C7H3NO4)(H2O)2]·2H2O}n, the MnII ion is coordinated in a distorted octahedral environment by the O atoms of two water molecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxylate (PDC) dianion, and two axial bridging carboxylate O atoms from two adjacent PDC ligands. The fully deprotonated PDC anion acts a
3-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several intermolecular O-H
O hydrogen bonds.
Online 20 September 2008
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