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Acta Cryst. (2008). E64, m1295-m1296  [ doi:10.1107/S1600536808029413 ]

catena-Poly[[[diaquamanganese(II)]-[mu]3-pyridine-2,3-dicarboxylato-[kappa]4N,O2:O3:O3'] dihydrate]

Z.-X. Du and J.-X. Li

Abstract: In the title coordination polymer, {[Mn(C7H3NO4)(H2O)2]·2H2O}n, the MnII ion is coordinated in a distorted octahedral environment by the O atoms of two water molecules, one N and one O atoms of the chelating pyridine-2,3-dicarboxylate (PDC) dianion, and two axial bridging carboxylate O atoms from two adjacent PDC ligands. The fully deprotonated PDC anion acts a [mu]3-bridging ligand, establishing a chain structure along the a axis. These polymeric chains are connected into a three-dimensional framework via several intermolecular O-H...O hydrogen bonds.

Online 20 September 2008


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