Received 19 September 2008
The title compound, C13H16N2O3S, is a thiourea derivative with benzoyl and propoxycarbonylmethyl groups attached to the two terminal N atoms. These groups adopt trans and cis configurations, respectively, with respect to the S atom across the thiourea C-N bonds. The compound crystallizes in the P21/c space group with Z = 8, resulting in two unique molecules in the asymmetric unit linked by C-HS and C-HO hydrogen bonds, forming a one-dimensional zigzag chain along the c axis.
For information on bond lengths and angles, see: Allen et al. (1987). For related literature on an analogous molecule, see: Hassan et al. (2008). For related structures, see: Yamin & Hassan (2004); Yamin & Yusof (2003).
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL, PARST (Nardelli, 1995) and PLATON (Spek, 2003).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: AT2635 ).
The authors thank Universiti Kebangsaan Malaysia for providing facilities, and the Ministry of Science, Technology and Innovation for research fund No. UKM-ST-01FRGS0016-2006.
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