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Acta Cryst. (2008). E64, m1462 [ doi:10.1107/S1600536808034016 ]
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O)bis(1-methylimidazole-2-carbaldehyde oximato-2N,O)manganese(III) perchlorateAbstract: In the title compound, [Mn(C5H6N3O)2(C3H7NO)]ClO4, the MnIII atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octahedral coordination geometry, formed by two N atoms and two O atoms from two 1-methylimidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethylformamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C-H
O hydrogen-bonding interactions.
Online 25 October 2008
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