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Acta Cryst. (2008). E64, m1447  [ doi:10.1107/S1600536808033552 ]

A new monoclinic polymorph of trans-dichloridodipyridinepalladium(II)

H. M. Lee and C.-Y. Liao

Abstract: In the structure of the title compound, [PdCl2(C5H5N)2], the PdII atom is located on an inversion centre and the pyridine rings are coplanar. There is intermolecular [pi]-[pi] stacking between the pyridyl rings, with a centroid-to-centroid separation of 3.916 (1) Å. The structure is a new polymorph of two previously determined structures [Viossat, Dung & Robert (1993). Acta Cryst. C49, 84-85; Liao & Lee (2006). Acta Cryst. E62, m680-m681].

Online 22 October 2008


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