Acta Cryst. (2008). E64, m1382  [ doi:10.1107/S1600536808032364 ]

[Bis(diphenylphosphino)methane-²P,P'][bis(diphenylphosphinomethyl)diethoxysilane-²P,P']bis(dinitrogen)molybdenum(0) benzene 0.7-solvate

K. Klatt, C. Näther and F. Tuczek

Abstract: In the crystal structure of the title compound, [Mo(C₂₅H₂₂P₂)(C₃₀H₃₄O₂P₂Si)(N₂)₂]·0.7C₆H₆, the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octahedral mode. The two C atoms of one of the two ethoxy groups are disordered and were refined using a split model and site-occupation factors of 0.7:0.3. The crystal structure contains a benzene solvent molecule with a site occupation of 70%.

Online 11 October 2008

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