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Acta Cryst. (2008). E64, o2146 [ doi:10.1107/S1600536808033825 ]
Abstract: The title compound, C7H8N2O3, crystallizes with two independent but essentially identical molecules in the asymmetric unit. Each molecule adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxylate group is twisted from the furan ring by 7.78 (13)° in one molecule and by 7.01 (17)° in the other. In the crystal structure, molecules are linked into chains running along [010] by bifurcated N-H
(N,O) and N-H
O hydrogen bonds. In addition, weak C-H
O interactions and an O
C short contact [2.896 (3) Å] are observed.
Online 22 October 2008
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