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Acta Cryst. (2008). E64, m1427-m1428  [ doi:10.1107/S1600536808033138 ]

(Benzene-1,3-dicarboxylato-[kappa]2O1,O1')(1,12,15,26-tetraaza-5,8,19,22-tetraoxa-3,4:9,10:17,18:23,24-tetrabenzocyclooctacosane-[kappa]4N1,N12,N15,N26)cadmium(II) benzene-1,3-dicarboxylic acid solvate

Z.-F. Jia, J.-F. Ma and L.-P. Zhang

Abstract: In the title compound, [Cd(C8H4O4)(C36H44N4O4)]·C8H6O4, the CdII atom is six-coordinated by four N atoms from the macrocyclic ligand and two O atoms from a benzene-1,3-dicarboxylate ligand. The complex molecules are linked by N-H...O hydrogen bonds, forming a one-dimensional chain structure along the b axis. The chains are further connected through N-H...O and O-H...O hydrogen bonds between the complex molecule and an uncoordinated benzene-1,3-dicarboxylic acid molecule, resulting in a two-dimensional supramolecular network.

Online 18 October 2008


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