Acta Cryst. (2008). E64, m1363  [ doi:10.1107/S1600536808031589 ]

Bis(acetylacetonato-²O,O')(methanol-O)(thiocyanato-N)manganese(III)

S.-M. Meng, H. Xie, Y.-Q. Fan and Y. Guo

Abstract: In the title complex, [Mn(C₅H₇O₂)₂(NCS)(CH₄O)], the Mn^III atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O-HS hydrogen bond, forming a chain running along [101].

Online 4 October 2008

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