Acta Cryst. (2008). E64, m1460  [ doi:10.1107/S1600536808034338 ]

Dichlorido{-6,6'-dimethoxy-2,2'-[o-phenylenebis(nitrilomethylidyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethylformamide solvate

H. Wang, D. Zhang, L. Tian and L.-F. Zhang

Abstract: In the heterodinuclear complex of the title compound, [PbZn(C₂₂H₁₈N₂O₄)Cl₂(C₂H₆OS)]·C₃H₇NO, the Zn^II atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb^II atom is coordinated in a distorted octahedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide molecule and one Cl atom. The dimethyl sulfoxide molecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).

Online 25 October 2008

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