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Acta Cryst. (2008). E64, m1450  [ doi:10.1107/S1600536808029462 ]

Di-[mu]-acetato-[kappa]3O,O':O;[kappa]3O:O,O'-bis[(acetato-[kappa]2O,O')(1,10-phenanthroline-[kappa]2N,N')cadmium(II)]

M. A. Harvey, S. Baggio, M. T. Garland and R. Baggio

Abstract: The title compound, [Cd2(C2H3O2)4(C12H8N2)2], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single [pi]-[pi] interaction between stacked phen groups [centroid-centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010).

Online 22 October 2008


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