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Acta Cryst. (2008). E64, m1394  [ doi:10.1107/S1600536808032303 ]

Bis{2-[(E)-benzyliminomethyl]-4,6-dibromophenolato-[kappa]2N,O}cobalt(II)

W. Jiang, G.-D. Mo and L. Jin

Abstract: In the title compound, [Co(C14H10Br2NO)2], the CoII ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyliminomethyl]-4,6-dibromophenolate ligands, displaying a distorted tetrahedral geometry. The CoII ion occupies a special position on a twofold rotation axis and thus the molecular symmetry of the complex is C2. The two phenolate rings are perpendicular [89.8 (3)°].

Online 15 October 2008


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