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Acta Cryst. (2008). E64, m1361-m1362  [ doi:10.1107/S1600536808031553 ]

[N,N,N',N'-Tetrakis(benzimidazol-2-ylmethyl)cyclohexane-1,2-diamine]nickel(II) dinitrate dihydrate

D. Zhan and Z.-A. Xiao

Abstract: In the title compound, [Ni(C38H38N10)](NO3)2·2H2O, the NiII ion is located on a crystallographic twofold rotation axis and is in a distorted octahedral coordination environment. The crystal structure is stablized by intermolecular N-H...O and C-H...O hydrogen bonds, and weak C-H...[pi] interactions. The O atoms of the unique nitrate ion are disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). In addition, the O atom of the unique solvent water molecule is disorded over two sites with equal occupancies.

Online 4 October 2008


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