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Acta Cryst. (2008). E64, m1386  [ doi:10.1107/S1600536808032297 ]

catena-Poly[[[2,6-bis(pyrazol-1-yl-[kappa]N2)pyridine-[kappa]N1](nitrato-[kappa]2O,O')cadmium(II)]-[mu]-thiocyanato-[kappa]2N:S]

Z. N. Yang and T. T. Sun

Abstract: In the title crystal structure, [Cd(NCS)(NO3)(C11H9N5)]n, the unique CdII ion is coordinated in a distorted pentagonal-bipyramidal environment. The axial thiocyanate ligands act in a [mu]1,3-bridging mode to connect symmetry-related CdII ions into one-dimensional chains along [010]. In addition, there are intermolecular C-H...O contacts between chains.

Online 11 October 2008


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