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Acta Cryst. (2008). E64, m1405 [ doi:10.1107/S1600536808032509 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
2P,P']rhodium(I) dichlorido[(1,2,5,6-![[eta]](/logos/entities/eta_rmgif.gif)
)-1,5-cyclooctadiene]rhodium(I)Abstract: In the title complex, [Rh(C6H16P2)2][RhCl2(C8H12)], the asymmetric unit contains two [Rh(dmpe)2] [dmpe = 1,2-bis(dimethylphosphino)ethane] half-cations, lying on inversion centers, and an [RhCl2(cod)]- (cod = 1,5-cyclooctadiene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic ![[pi]](/logos/entities/pi_rmgif.gif)
-bonds of the cyclooctadiene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual interactions.
Online 15 October 2008
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