catena-Poly[[[diaqua­lanthanum(III)]-tetra­kis[μ-N-(4-acetamido­phenyl­sulfon­yl)­glycinato]-[diaqua­lanthanum(III)]-bis­[μ-N-(4-acetamido­phenyl­sulfon­yl)­glycinato]] 4,4′-bipyridine disolvate tetra­deca­hydrate]

Wang, J.-G.; Qin, J.-H.

doi:10.1107/S1600536808031450

Volume 64
Part 11
Pages m1364-m1365
November 2008

Received 17 September 2008
Accepted 29 September 2008
Online 4 October 2008

Key indicators
Single-crystal X-ray study
T = 291 K
Mean (C-C) = 0.005 Å
R = 0.032
wR = 0.072
Data-to-parameter ratio = 14.6
Details

catena-Poly[[[diaqualanthanum(III)]-tetrakis[-N-(4-acetamidophenylsulfonyl)glycinato]-[diaqualanthanum(III)]-bis[-N-(4-acetamidophenylsulfonyl)glycinato]] 4,4'-bipyridine disolvate tetradecahydrate]

Jian-Ge Wang ^a ^* and Jian-Hua Qin ^a

^aCollege of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, People's Republic of China
Correspondence e-mail: jh_q128105@126.com

In the title compound, {[La₂(C₁₀H₁₁N₂O₅S)₆(H₂O)₄]·2C₁₀H₈N₂·14H₂O}_n, the La^III ions are in a slightly distorted bicapped trigonal prismatic geometry, and are linked by six carboxylate groups in a syn-syn bidentate bridging fashion to form a one-dimensional inorganic-organic alternating linear chain. These polymeric chains generate microchannels extending along [100], and these cavities are occupied by discrete tetradecameric water clusters, which interact with their surroundings and finally furnish the three-dimensional supramolecular network via 15 O-HO, one O-HS, two O-HN and six N-HO classical hydrogen bonds. 4,4-Bipyridine acts as an inserting component and hydrogen-bond acceptor, and it is a nonplanar molecule with a dihedral angle of 33.12 (13)° between the pyridine rings. Owing to the numerous classical hydrogen bonds, the observed weak intermolecular C-HO, C-H [pi] and [pi] - [pi] stacking interactions can be neglected with regard to stabilizing the network.

Related literature

For the structure of a related complex, see: Hu et al. (2007). For other related literature on lanthanides, see: Guo et al. (2005); Pan et al. (2003); Zhao et al. (2004); Zheng et al. (2004).

Experimental

Crystal data

[La₂(C₁₀H₁₁N₂O₅S)₆(H₂O)₄]·2C₁₀H₈N₂·14H₂O
M_r = 2542.08
Triclinic, $[P \overline 1]$
a = 9.6379 (8) Å
b = 16.9589 (13) Å
c = 17.6005 (14) Å
= 99.971 (1)°
= 105.758 (1)°
= 93.692 (1)°
V = 2707.9 (4) Å³
Z = 1
Mo K radiation
= 0.99 mm^-1
T = 291 (2) K
0.25 × 0.13 × 0.08 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 1997) T_min = 0.790, T_max = 0.925
20875 measured reflections
10013 independent reflections
8632 reflections with I > 2(I)
R_int = 0.028

Refinement

R[F² > 2(F²)] = 0.032
wR(F²) = 0.072
S = 1.02
10013 reflections
688 parameters
H-atom parameters constrained
_max = 0.39 e Å^-3
_min = -0.48 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
O1-H1WO23ⁱ	0.82	2.11	2.872 (3)	153
O1-H2WO2ⁱⁱ	0.83	1.99	2.818 (3)	179
O2-H3WN2	0.84	2.00	2.827 (4)	171
O2-H4WO4ⁱⁱ	0.83	1.98	2.744 (3)	154
O3-H5WO9ⁱⁱⁱ	0.85	1.98	2.801 (4)	162
O3-H6WO14^iv	0.84	1.94	2.772 (3)	175
O4-H7WN1^v	0.83	1.99	2.781 (4)	158
O4-H8WO12^vi	0.82	2.41	3.166 (3)	154
O4-H8WS1^vi	0.82	2.94	3.711 (3)	156
O5-H9WO4	0.84	2.04	2.865 (4)	167
O5-H10WO11	0.83	2.03	2.844 (4)	168
O6-H11WO5	0.84	1.91	2.716 (4)	160
O6-H12WO18	0.84	2.01	2.805 (3)	158
O7-H13WO13	0.83	2.12	2.914 (4)	160
O7-H14WO6	0.84	2.00	2.810 (4)	165
O8-H15WO19^v	0.83	2.00	2.722 (4)	145
O8-H16WO7	0.91	1.88	2.708 (4)	151
O9-H17WO8	0.83	2.00	2.751 (4)	151
N3-H3O6^vii	0.86	2.15	3.007 (4)	171
N4-H4O16^viii	0.85	2.30	3.151 (3)	173
N5-H5O3^vii	0.86	2.06	2.921 (4)	177
N6-H6O20	0.86	2.19	3.040 (3)	169
N7-H7O8^ix	0.86	2.02	2.878 (4)	172
N8-H8O17	0.86	2.33	2.974 (3)	131
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x, -y+1, -z; (iii) -x+2, -y+2, -z+1; (iv) -x+2, -y+1, -z+1; (v) x, y+1, z; (vi) x-1, y, z; (vii) -x+1, -y+1, -z+1; (viii) x+1, y, z; (ix) x, y-1, z.

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SI2111 ).

Acknowledgements

The authors thank Luo Yang Normal University for supporting thise work.

References

Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Guo, X.-D., Zhu, G.-S., Fang, Q.-R., Xue, M., Tian, G., Sun, J.-Y. & Li, X.-T. (2005). Inorg. Chem. 44, 3850-3855.
Hu, D.-X., Chen, P.-K., Luo, F., Che, Y.-X. & Zheng, J.-M. J. (2007). J. Mol. Struct. 837, 179-184.
Pan, L., Adams, K.-M., Hernandez, H.-E., Wang, X.-T., Zheng, C., Hattori, Y. & Kaneko, K. (2003). J. Am. Chem. Soc. 125, 3062-3067.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Zhao, B., Cheng, P., Chen, X.-Y., Shi, W., Liao, D.-Z., Yan, S.-P. & Jiang, Z.-H. (2004). J. Am. Chem. Soc. 126, 3012-3013.
Zheng, X.-J., Sun, C.-Y., Lu, S.-Z., Liao, F.-H., Gao, S. & Jin, L.-P. (2004). Eur. J. Inorg. Chem. pp.3262-3268.

metal-organic compounds