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Acta Cryst. (2008). E64, m1534 [ doi:10.1107/S1600536808036465 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
5C-chlorido-1Cl-bis[1(![[eta]](/logos/entities/eta_rmgif.gif)
5)-cyclopentadienyl](![[mu]](/logos/entities/mu_rmgif.gif)
-![[alpha]](/logos/entities/alpha_rmgif.gif)
-oxidobenzylidene-1:22O:C)titanium(IV)tungsten(0)Abstract: The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclopentadienyl rings undergoes an offset face-to-face ![[pi]](/logos/entities/pi_rmgif.gif)
- interaction [3.544 (6) Å] with the symmetry-related cyclopentadienyl ring of a neighbouring molecule.
Online 13 November 2008
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