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Acta Cryst. (2008). E64, m1574-m1575 [ doi:10.1107/S1600536808036908 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-3-carboxybenzoato)bis(1,10-phenanthroline)tricopper(II)]-di-3-isophthalato]Abstract: The title copper coordination polymer, [Cu3(C8H4O4)2(C8H5O4)2(C10H8N2)2]n, was synthesized by reacting Cu(NO3)2, isophthalic acid and 1,10-phenanthroline under hydrothermal conditions. The trinuclear unit presents a central almost planar CuO4 chromophore with the cation on a symmetry center, and two symmetry-related CuN2O3 groups with the metal centre in a distorted square-pyramidal environment. These units are bridged by isophthalate ligands into one-dimensional double-chain coordination polymers which are, in turn, connected by various ![[pi]](/logos/entities/pi_rmgif.gif)
- stacking interactions (face-to-face distance ca 3.45 Å) and O-H
O hydrogen bonds, forming a three-dimensional supramolecular network.
Online 20 November 2008
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