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Acta Cryst. (2008). E64, m1499 [ doi:10.1107/S1600536808035162 ]
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N)methylamine]cobalt(III)Abstract: The title compound, [Co(N3)3(C16H14N4)], was synthesized by hydrothermal reaction of [Co(NH3)6](NO3)3, NaN3 and tris(2-pyridyl)methylamine. The structure contains two independent complexes in the asymmetric unit, with closely comparable geometry. The CoIII atoms are hexacoordinated by three N atoms from the tridentate tris(2-pyridyl)methylamine ligands and three azide ions in a fac arrangement. N-H
N hydrogen bonds are formed between the amino group and the uncoordinated terminal N atoms of the azide ligands.
Online 8 November 2008
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