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Acta Cryst. (2008). E64, m1577 [ doi:10.1107/S1600536808037744 ]
![[kappa]](/logos/entities/kappa_rmgif.gif)
2N,N')copper(I)]-![[mu]](/logos/entities/mu_rmgif.gif)
-thiocyanato-2N:S-[(1,10-phenanthroline-2N,N')copper(I)]--cyanido-2N:C]Abstract: In the title complex, [Cu2(CN)(NCS)(C12H8N2)2], which was synthesized under hydrothermal conditions, both CuI atoms have a slightly distorted tetrahedral geometry. They are coordinated by two N atoms of one 1,10-phenanthroline ligand, one bridging thiocyanate anion and one bridging cyanide anion. In the crystal structure, infinite helical {Cu-CN-Cu-SCN}n chains are formed along [
01].
Online 20 November 2008
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