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Acta Cryst. (2008). E64, m1571  [ doi:10.1107/S1600536808037902 ]

Di-[mu]1,1-azido-bis[azido(5,5'-dimethyl-2,2'-bipyridine)nickel(II)]

J. Hou

Abstract: In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni2(N3)4(C12H12N2)2], the NiII atom is five-coordinated by two N atoms of the 5,5'-dimethyl-2,2'-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal-bipyramidal geometry. The Ni...Ni distance is 3.2398 (12) Å.

Online 20 November 2008


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