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Acta Cryst. (2008). E64, m1589 [ doi:10.1107/S1600536808038063 ]
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-2-anilinobenzoato)bis[methanolcopper(II)](Cu-Cu)Abstract: The title compound, [Cu2(C13H10NO2)4(CH4O)2], has been prepared by the reaction of 2-anilinobenzoic acid, HL, with copper(II) nitrate in methanol. This dinuclear complex is arranged around an inversion center. Each Cu atom displays a distorted trigonal-pyramidal coordination with four O atoms from the four ligands L and one axial O atom of the methanol solvent molecule. Each carboxylate group of the ligands L links two Cu atoms, building a dinuclear complex with a Cu-Cu distance of 2.5774 (10) Å. There are intramolecular N-H
O hydrogen bonds, and the H atom of the methanol molecule is involved in weak bifurcated hydrogen-bonding interactions with two carboxylate O atoms of related molecules, forming a chain developing parallel to the a axis.
Online 22 November 2008
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