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Acta Cryst. (2008). E64, m1500    [ doi:10.1107/S1600536808035150 ]

catena-Poly[[aqua(2,2'-bipyridine-[kappa]2N,N')copper(II)]-[mu]-5-nitroisophthalato-[kappa]3O1,O1':O3]

L. Hao and X. Liu

Abstract top

In the asymmetric unit of the title compound, [Cu(C8H3NO6)(C10H8N2)(H2O)]n, there are two symmetry-independent one-dimensional coordination polymers related by a non-crystallographic inversion center. Within the polymers, the CuII atoms, coordinated by the water molecule and the chelating 2,2'-bipyridine ligands, are bridged by 5-nitrobenzene-1,3-dicarboxylate dianions which act as tridentate ligands; the carboxylate groups exhibit monodentate and symmetric bidentate coordination modes. The CuII atoms show a strongly distorted octahedral coordination geometry. In the crystal structure, the two symmetry-independent coordination polymers form another one-dimensional polymeric structure via O-H...O hydrogen bonds between coordinated water molecules and carboxylate groups.

Comment top

In recent years, carboxylic acids have been widely used as polydentate ligands, which can coordinate to transition or rare earth ions yielding complexes with interesting properties that are useful in materials science (Church & Halvorson, 1959) and in biological systems (Okabe & Oya, 2000). For example, Kim et al. (2001) focused on the syntheses of transition metal complexes containing benzene carboxylate and rigid aromatic pyridine ligands in order to study their electronic conductivity and magnetic properties. The importance of transition metal dicarboxylate complexes motivated us to pursue synthetic strategies for these compounds, using 5-nitroisophthalic acid as a polydentate ligand. Here we report the synthesis and X-ray crystal structure analysis of the title compound.

The molecular structure of the title compound is shown in Fig. 1. The title compound, [Cu(C8H3NO6)(C10H8N2)(H2O)]n is a one-dimensional coordination polymer (Fig. 2). There are two symmetry independent 1D polymers in the crystal. The Cu(II) atom shows a strongly disordered coordination geometry. It is coordinated by two carboxylate groups from two different 5-nitroisophthalate ligands, 2,2'-bipyridyl and water molecule. The carboxylate groups act in a monodentate and bidentate coordination modes.The symmetry independent polymeric chains are linked via O-H···O hydrogen bonds (Table 1).

Related literature top

For the uses of carboxylic acids in materials science, see: Church & Halvorson (1959), and in biological systems, see: Okabe & Oya (2000); Kim et al. (2001).

Experimental top

A mixture of copper dichloride (0.5 mmol), 2,2'-bipyridine (0.5 mmol), and 5-nitroisophthalic acid (0.5 mmol) in H2O (8 ml) and ethanol (8 ml) was sealed in a 25 ml Teflon-lined stainless steel autoclave and kept at 413 K for three days. Blue crystals were obtained after cooling to room temperature (yield 27%). Anal. Calc. for C18H13CuN3O7: C 48.34, H 2.91, N 10.74%; Found: C 48.30, H 2.84, N 10.69%.

Refinement top

The H atoms of water molecule were located from difference Fourier maps and were refined with distance restraints: d(H–H) = 1.38 (2) Å, d(O–H) = 0.88 (2) Å, and with a fixed Uiso of 0.080 Å2. All other H atoms were placed in calculated positions with a C—H bond distance of 0.93 Å and refined in the riding model approximation with Uiso(H) = 1.2Ueq of the carrier atom.

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT-Plus (Bruker, 2001); data reduction: SAINT-Plus (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. A view of the title structure showing the atomic numbering scheme and 30% probability displacement ellipsoids.
[Figure 2] Fig. 2. One of the symmetry-independent coordination polymers
catena-Poly[[aqua(2,2'-bipyridine-κ2N,N')copper(II)]- µ-5-nitroisophthalato-κ3O1,O1':O3] top
Crystal data top
[Cu(C8H3NO6)(C10H8N2)(H2O)]F(000) = 1816
Mr = 446.85Dx = 1.627 Mg m−3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6694 reflections
a = 10.1326 (10) Åθ = 1.8–25.5°
b = 23.263 (3) ŵ = 1.25 mm−1
c = 15.6087 (15) ÅT = 293 K
β = 97.28 (2)°Block, blue
V = 3649.6 (7) Å30.12 × 0.10 × 0.08 mm
Z = 8
Data collection top
Bruker APEXII CCD area-detector
diffractometer		6694 independent reflections
Radiation source: fine-focus sealed tube5089 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.025
φ and ω scansθmax = 25.5°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		h = −12→10
Tmin = 0.865, Tmax = 0.907k = −28→22
18862 measured reflectionsl = −18→18
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.124H atoms treated by a mixture of independent and constrained refinement
S = 1.00 w = 1/[σ2(Fo2) + (0.075P)2 + 2.4671P]
where P = (Fo2 + 2Fc2)/3
6694 reflections(Δ/σ)max = 0.003
535 parametersΔρmax = 0.83 e Å−3
6 restraintsΔρmin = −0.40 e Å−3
Crystal data top
[Cu(C8H3NO6)(C10H8N2)(H2O)]V = 3649.6 (7) Å3
Mr = 446.85Z = 8
Monoclinic, P21/nMo Kα radiation
a = 10.1326 (10) ŵ = 1.25 mm−1
b = 23.263 (3) ÅT = 293 K
c = 15.6087 (15) Å0.12 × 0.10 × 0.08 mm
β = 97.28 (2)°
Data collection top
Bruker APEXII CCD area-detector
diffractometer		6694 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 2001)		5089 reflections with I > 2σ(I)
Tmin = 0.865, Tmax = 0.907Rint = 0.025
18862 measured reflectionsθmax = 25.5°
Refinement top
R[F2 > 2σ(F2)] = 0.042H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.124Δρmax = 0.83 e Å−3
S = 1.00Δρmin = −0.40 e Å−3
6694 reflectionsAbsolute structure: ?
535 parametersFlack parameter: ?
6 restraintsRogers parameter: ?
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cu11.16168 (4)0.154431 (15)0.85573 (3)0.02711 (13)
Cu20.12372 (4)0.354405 (16)0.93350 (3)0.03053 (13)
C11.1959 (4)0.07213 (16)1.0079 (2)0.0457 (9)
H11.21450.10481.04160.055*
C21.2039 (5)0.0193 (2)1.0471 (3)0.0635 (13)
H21.22680.01611.10650.076*
C31.1773 (5)−0.02890 (18)0.9970 (3)0.0634 (13)
H31.1810−0.06511.02240.076*
C41.1452 (4)−0.02334 (16)0.9089 (3)0.0481 (10)
H41.1282−0.05560.87410.058*
C51.1388 (3)0.03117 (13)0.8732 (2)0.0291 (7)
C61.1072 (3)0.04138 (13)0.7785 (2)0.0266 (7)
C71.0796 (3)−0.00183 (15)0.7180 (2)0.0376 (8)
H71.0788−0.04010.73540.045*
C81.0527 (4)0.01249 (16)0.6306 (2)0.0408 (9)
H81.0328−0.01600.58910.049*
C91.0562 (4)0.06932 (16)0.6068 (2)0.0415 (9)
H91.03830.08000.54910.050*
C101.0866 (3)0.11017 (14)0.6700 (2)0.0337 (8)
H101.08890.14860.65360.040*
C110.3761 (3)0.19406 (14)0.8105 (2)0.0284 (7)
C120.8756 (3)0.17568 (14)0.8380 (2)0.0286 (7)
C130.7500 (3)0.20954 (13)0.80617 (19)0.0232 (6)
C140.6258 (3)0.18759 (13)0.8202 (2)0.0252 (6)
H140.62130.15260.84840.030*
C150.5081 (3)0.21767 (13)0.79223 (19)0.0228 (6)
C160.5143 (3)0.27058 (14)0.7520 (2)0.0287 (7)
H160.43750.29120.73320.034*
C170.6391 (3)0.29176 (14)0.7409 (2)0.0300 (7)
C180.7573 (3)0.26273 (13)0.7665 (2)0.0268 (7)
H180.83880.27840.75740.032*
C190.0858 (4)0.43908 (16)0.7844 (3)0.0419 (9)
H190.07170.40660.74970.050*
C200.0710 (4)0.49282 (18)0.7464 (3)0.0506 (10)
H200.04930.49650.68690.061*
C210.0891 (4)0.54045 (17)0.7982 (3)0.0530 (11)
H210.08010.57700.77410.064*
C220.1206 (3)0.53393 (15)0.8859 (3)0.0437 (9)
H220.13120.56600.92170.052*
C230.1365 (3)0.47885 (13)0.9207 (2)0.0331 (8)
C240.1701 (3)0.46692 (14)1.0141 (2)0.0312 (7)
C250.1994 (4)0.50930 (15)1.0773 (3)0.0450 (10)
H250.19760.54801.06200.054*
C260.2313 (4)0.49311 (18)1.1632 (3)0.0505 (10)
H260.25020.52091.20590.061*
C270.2346 (4)0.43618 (19)1.1844 (3)0.0502 (10)
H270.25730.42451.24140.060*
C280.2036 (4)0.39641 (17)1.1200 (2)0.0423 (9)
H280.20480.35771.13480.051*
C290.4118 (3)0.33262 (14)0.9445 (2)0.0276 (7)
C300.5355 (3)0.29913 (13)0.9800 (2)0.0245 (7)
C310.6609 (3)0.31950 (13)0.9659 (2)0.0247 (6)
H310.66680.35290.93390.030*
C320.7773 (3)0.29078 (12)0.9988 (2)0.0230 (6)
C330.7701 (3)0.24090 (13)1.0462 (2)0.0281 (7)
H330.84660.22131.06870.034*
C340.6445 (3)0.22111 (13)1.0589 (2)0.0274 (7)
C350.5281 (3)0.24928 (14)1.0278 (2)0.0273 (7)
H350.44610.23501.03870.033*
C360.9110 (3)0.31370 (13)0.9804 (2)0.0265 (7)
N11.1618 (3)0.07821 (11)0.92194 (18)0.0308 (6)
N21.1133 (2)0.09711 (10)0.75448 (17)0.0256 (6)
N30.1197 (3)0.43222 (12)0.86995 (18)0.0310 (6)
N40.1716 (3)0.41090 (11)1.03653 (19)0.0315 (6)
N50.6350 (3)0.16771 (13)1.1080 (2)0.0421 (8)
N60.6481 (4)0.34942 (14)0.7038 (2)0.0526 (9)
O10.0918 (2)0.30549 (9)0.81941 (17)0.0320 (5)
O20.3006 (2)0.31188 (9)0.96166 (16)0.0358 (6)
O30.4241 (3)0.37683 (12)0.90419 (19)0.0532 (7)
O40.9139 (2)0.35925 (10)0.93797 (18)0.0392 (6)
O51.0167 (2)0.28721 (10)1.00723 (16)0.0360 (6)
O60.5265 (3)0.14511 (15)1.1064 (3)0.0852 (13)
O70.7369 (3)0.14842 (12)1.1487 (2)0.0579 (8)
O80.5457 (3)0.37104 (19)0.6687 (4)0.128 (2)
O90.7554 (3)0.37294 (13)0.7091 (2)0.0734 (10)
O100.9862 (2)0.19817 (9)0.82626 (16)0.0328 (5)
O110.8637 (3)0.12791 (13)0.8686 (2)0.0653 (9)
O121.1948 (2)0.20384 (9)0.97015 (16)0.0319 (5)
O130.2693 (2)0.22031 (10)0.78406 (16)0.0369 (6)
O140.3736 (2)0.14837 (10)0.85273 (17)0.0390 (6)
H1W1.245 (4)0.2303 (13)0.960 (3)0.080*
H2W1.132 (3)0.2151 (17)0.994 (3)0.080*
H3W0.157 (3)0.2969 (18)0.795 (3)0.080*
H4W0.042 (4)0.2781 (13)0.824 (3)0.080*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cu10.0215 (2)0.0234 (2)0.0363 (2)0.00148 (15)0.00314 (16)0.00163 (15)
Cu20.0210 (2)0.0245 (2)0.0466 (3)0.00113 (15)0.00654 (18)0.00113 (16)
C10.065 (3)0.041 (2)0.031 (2)0.0004 (19)0.0076 (18)0.0047 (16)
C20.096 (4)0.060 (3)0.033 (2)0.006 (3)0.007 (2)0.014 (2)
C30.092 (4)0.040 (2)0.059 (3)0.004 (2)0.012 (3)0.031 (2)
C40.063 (3)0.0273 (18)0.053 (3)−0.0023 (17)0.005 (2)0.0101 (16)
C50.0230 (16)0.0246 (16)0.0396 (19)−0.0009 (12)0.0039 (14)0.0044 (13)
C60.0201 (15)0.0235 (15)0.0361 (18)−0.0006 (12)0.0037 (13)0.0017 (13)
C70.0313 (18)0.0270 (17)0.054 (2)−0.0024 (14)0.0052 (16)−0.0048 (16)
C80.036 (2)0.043 (2)0.042 (2)−0.0019 (16)0.0012 (16)−0.0122 (16)
C90.041 (2)0.048 (2)0.034 (2)0.0023 (17)−0.0006 (16)−0.0037 (16)
C100.0362 (19)0.0319 (17)0.0323 (19)0.0054 (14)0.0015 (15)0.0049 (14)
C110.0197 (16)0.0332 (17)0.0332 (18)−0.0034 (13)0.0071 (13)−0.0116 (14)
C120.0172 (16)0.0347 (18)0.0332 (18)0.0028 (13)0.0008 (13)0.0056 (14)
C130.0147 (14)0.0287 (16)0.0257 (16)0.0017 (12)0.0008 (12)0.0000 (12)
C140.0219 (16)0.0261 (15)0.0283 (16)−0.0010 (12)0.0054 (13)−0.0006 (13)
C150.0156 (14)0.0280 (15)0.0252 (16)−0.0013 (12)0.0041 (12)−0.0061 (12)
C160.0173 (15)0.0372 (18)0.0314 (18)0.0093 (13)0.0027 (13)0.0019 (14)
C170.0269 (17)0.0298 (16)0.0343 (18)0.0035 (13)0.0078 (14)0.0110 (13)
C180.0156 (14)0.0337 (17)0.0314 (18)−0.0016 (12)0.0039 (12)0.0049 (13)
C190.040 (2)0.040 (2)0.049 (2)0.0029 (16)0.0137 (17)0.0071 (17)
C200.043 (2)0.058 (3)0.052 (2)0.0069 (19)0.0135 (19)0.024 (2)
C210.040 (2)0.034 (2)0.088 (3)0.0026 (17)0.021 (2)0.027 (2)
C220.031 (2)0.0237 (17)0.078 (3)0.0018 (14)0.0160 (19)0.0050 (18)
C230.0160 (15)0.0232 (16)0.062 (2)0.0000 (12)0.0137 (15)0.0010 (15)
C240.0149 (15)0.0292 (17)0.051 (2)−0.0005 (12)0.0090 (14)−0.0043 (15)
C250.032 (2)0.0279 (18)0.077 (3)−0.0019 (15)0.0121 (19)−0.0106 (18)
C260.034 (2)0.059 (3)0.058 (3)−0.0019 (18)0.0037 (19)−0.021 (2)
C270.039 (2)0.064 (3)0.048 (2)0.0050 (19)0.0075 (18)−0.006 (2)
C280.037 (2)0.043 (2)0.047 (2)0.0056 (17)0.0058 (17)−0.0007 (17)
C290.0166 (15)0.0327 (17)0.0326 (18)0.0031 (13)−0.0002 (13)−0.0046 (14)
C300.0155 (15)0.0300 (16)0.0279 (17)0.0005 (12)0.0024 (12)−0.0048 (12)
C310.0192 (15)0.0241 (15)0.0312 (17)−0.0012 (12)0.0053 (12)−0.0004 (12)
C320.0156 (15)0.0266 (15)0.0276 (16)−0.0004 (11)0.0059 (12)−0.0043 (12)
C330.0187 (15)0.0345 (17)0.0305 (18)0.0020 (13)0.0017 (13)0.0005 (13)
C340.0216 (16)0.0316 (16)0.0288 (17)−0.0020 (13)0.0027 (13)0.0043 (13)
C350.0175 (15)0.0342 (17)0.0307 (18)−0.0059 (13)0.0050 (13)0.0015 (13)
C360.0140 (15)0.0294 (16)0.0370 (18)0.0009 (12)0.0073 (13)−0.0085 (14)
N10.0305 (15)0.0280 (14)0.0347 (16)−0.0011 (11)0.0068 (12)0.0048 (11)
N20.0213 (13)0.0233 (13)0.0320 (15)0.0026 (10)0.0030 (11)−0.0005 (11)
N30.0216 (14)0.0277 (14)0.0446 (18)0.0022 (11)0.0075 (12)0.0052 (12)
N40.0239 (14)0.0268 (14)0.0445 (18)0.0028 (11)0.0071 (12)−0.0015 (12)
N50.0325 (17)0.0448 (18)0.0488 (19)−0.0039 (14)0.0042 (14)0.0181 (14)
N60.044 (2)0.049 (2)0.068 (2)0.0143 (16)0.0185 (17)0.0321 (17)
O10.0243 (12)0.0261 (12)0.0455 (14)0.0024 (9)0.0044 (10)−0.0001 (10)
O20.0148 (11)0.0301 (12)0.0621 (16)0.0023 (9)0.0033 (10)−0.0029 (11)
O30.0327 (14)0.0511 (17)0.075 (2)0.0086 (12)0.0035 (13)0.0290 (15)
O40.0241 (12)0.0291 (12)0.0669 (17)−0.0021 (9)0.0153 (12)0.0085 (11)
O50.0157 (11)0.0366 (12)0.0564 (16)0.0029 (9)0.0072 (10)−0.0003 (11)
O60.0464 (19)0.086 (2)0.116 (3)−0.0290 (17)−0.0150 (19)0.065 (2)
O70.0401 (16)0.0511 (17)0.083 (2)0.0105 (13)0.0080 (15)0.0336 (15)
O80.046 (2)0.117 (3)0.226 (5)0.037 (2)0.036 (3)0.131 (4)
O90.061 (2)0.0534 (18)0.102 (3)−0.0163 (16)−0.0027 (19)0.0388 (18)
O100.0121 (10)0.0274 (11)0.0583 (15)0.0017 (8)0.0015 (10)−0.0021 (10)
O110.0313 (15)0.0648 (19)0.101 (2)0.0135 (13)0.0130 (15)0.0564 (18)
O120.0267 (12)0.0261 (11)0.0415 (14)0.0039 (9)−0.0003 (10)−0.0027 (10)
O130.0157 (11)0.0404 (13)0.0550 (16)0.0031 (10)0.0066 (10)−0.0012 (11)
O140.0223 (12)0.0378 (14)0.0583 (16)−0.0027 (10)0.0103 (11)0.0048 (11)
Geometric parameters (Å, º) top
Cu1—O102.049 (2)C19—N31.345 (5)
Cu1—N12.052 (3)C19—C201.384 (5)
Cu1—N22.078 (3)C19—H190.9300
Cu1—O122.115 (2)C20—C211.371 (6)
Cu1—O14i2.158 (2)C20—H200.9300
Cu1—O13i2.258 (2)C21—C221.374 (6)
Cu2—O22.046 (2)C21—H210.9300
Cu2—N32.062 (3)C22—C231.393 (5)
Cu2—N42.086 (3)C22—H220.9300
Cu2—O12.104 (2)C23—N31.341 (4)
Cu2—O4ii2.139 (2)C23—C241.481 (5)
Cu2—O5ii2.294 (2)C24—N41.349 (4)
C1—N11.350 (5)C24—C251.400 (5)
C1—C21.372 (6)C25—C261.391 (6)
C1—H10.9300C25—H250.9300
C2—C31.373 (6)C26—C271.364 (6)
C2—H20.9300C26—H260.9300
C3—C41.379 (6)C27—C281.373 (6)
C3—H30.9300C27—H270.9300
C4—C51.383 (5)C28—N41.346 (5)
C4—H40.9300C28—H280.9300
C5—N11.337 (4)C29—O31.220 (4)
C5—C61.491 (5)C29—O21.284 (4)
C6—N21.353 (4)C29—C301.520 (4)
C6—C71.383 (5)C30—C351.386 (4)
C7—C81.398 (5)C30—C311.400 (4)
C7—H70.9300C31—C321.395 (4)
C8—C91.375 (5)C31—H310.9300
C8—H80.9300C32—C331.382 (4)
C9—C101.375 (5)C32—C361.518 (4)
C9—H90.9300C33—C341.391 (4)
C10—N21.347 (4)C33—H330.9300
C10—H100.9300C34—C351.383 (4)
C11—O141.253 (4)C34—N51.470 (4)
C11—O131.265 (4)C35—H350.9300
C11—C151.506 (4)C36—O41.252 (4)
C12—O111.222 (4)C36—O51.260 (4)
C12—O101.271 (4)N5—O61.216 (4)
C12—C131.525 (4)N5—O71.226 (4)
C13—C181.390 (4)N6—O91.211 (4)
C13—C141.401 (4)N6—O81.218 (4)
C14—C151.404 (4)O1—H3W0.83 (3)
C14—H140.9300O1—H4W0.82 (3)
C15—C161.387 (4)O4—Cu2i2.139 (2)
C16—C171.388 (5)O5—Cu2i2.294 (2)
C16—H160.9300O12—H1W0.82 (4)
C17—C181.389 (4)O12—H2W0.82 (4)
C17—N61.468 (4)O13—Cu1ii2.258 (2)
C18—H180.9300O14—Cu1ii2.158 (2)
O10—Cu1—N1119.16 (10)N3—C19—C20122.2 (4)
O10—Cu1—N291.92 (10)N3—C19—H19118.9
N1—Cu1—N279.26 (10)C20—C19—H19118.9
O10—Cu1—O1287.71 (9)C21—C20—C19118.5 (4)
N1—Cu1—O1293.12 (10)C21—C20—H20120.7
N2—Cu1—O12171.06 (10)C19—C20—H20120.7
O10—Cu1—O14i149.84 (9)C20—C21—C22119.7 (3)
N1—Cu1—O14i90.99 (10)C20—C21—H21120.1
N2—Cu1—O14i94.65 (10)C22—C21—H21120.1
O12—Cu1—O14i90.11 (10)C21—C22—C23119.4 (4)
O10—Cu1—O13i90.66 (9)C21—C22—H22120.3
N1—Cu1—O13i150.04 (10)C23—C22—H22120.3
N2—Cu1—O13i98.11 (10)N3—C23—C22120.9 (4)
O12—Cu1—O13i90.83 (9)N3—C23—C24115.2 (3)
O14i—Cu1—O13i59.29 (8)C22—C23—C24123.8 (3)
O2—Cu2—N3119.41 (10)N4—C24—C25120.2 (3)
O2—Cu2—N491.57 (10)N4—C24—C23115.5 (3)
N3—Cu2—N478.83 (11)C25—C24—C23124.3 (3)
O2—Cu2—O187.52 (9)C26—C25—C24119.4 (4)
N3—Cu2—O194.37 (10)C26—C25—H25120.3
N4—Cu2—O1171.62 (10)C24—C25—H25120.3
O2—Cu2—O4ii149.99 (9)C27—C26—C25119.5 (4)
N3—Cu2—O4ii90.60 (9)C27—C26—H26120.3
N4—Cu2—O4ii94.38 (10)C25—C26—H26120.3
O1—Cu2—O4ii90.54 (10)C26—C27—C28118.7 (4)
O2—Cu2—O5ii91.14 (9)C26—C27—H27120.6
N3—Cu2—O5ii149.09 (9)C28—C27—H27120.6
N4—Cu2—O5ii96.95 (10)N4—C28—C27123.0 (4)
O1—Cu2—O5ii91.40 (9)N4—C28—H28118.5
O4ii—Cu2—O5ii58.96 (8)C27—C28—H28118.5
N1—C1—C2122.1 (4)O3—C29—O2125.0 (3)
N1—C1—H1119.0O3—C29—C30119.1 (3)
C2—C1—H1119.0O2—C29—C30115.9 (3)
C1—C2—C3118.7 (4)C35—C30—C31118.7 (3)
C1—C2—H2120.6C35—C30—C29121.8 (3)
C3—C2—H2120.6C31—C30—C29119.5 (3)
C2—C3—C4119.7 (4)C32—C31—C30121.5 (3)
C2—C3—H3120.1C32—C31—H31119.3
C4—C3—H3120.1C30—C31—H31119.3
C3—C4—C5118.8 (4)C33—C32—C31120.0 (3)
C3—C4—H4120.6C33—C32—C36120.3 (3)
C5—C4—H4120.6C31—C32—C36119.7 (3)
N1—C5—C4121.7 (3)C32—C33—C34117.7 (3)
N1—C5—C6115.7 (3)C32—C33—H33121.1
C4—C5—C6122.6 (3)C34—C33—H33121.1
N2—C6—C7121.3 (3)C35—C34—C33123.2 (3)
N2—C6—C5114.6 (3)C35—C34—N5118.3 (3)
C7—C6—C5124.1 (3)C33—C34—N5118.4 (3)
C6—C7—C8119.4 (3)C34—C35—C30118.9 (3)
C6—C7—H7120.3C34—C35—H35120.5
C8—C7—H7120.3C30—C35—H35120.5
C9—C8—C7118.9 (3)O4—C36—O5121.0 (3)
C9—C8—H8120.5O4—C36—C32118.6 (3)
C7—C8—H8120.5O5—C36—C32120.4 (3)
C8—C9—C10118.8 (3)O4—C36—Cu2i57.03 (16)
C8—C9—H9120.6O5—C36—Cu2i64.09 (16)
C10—C9—H9120.6C32—C36—Cu2i174.0 (2)
N2—C10—C9123.0 (3)C5—N1—C1119.0 (3)
N2—C10—H10118.5C5—N1—Cu1115.6 (2)
C9—C10—H10118.5C1—N1—Cu1125.1 (2)
O14—C11—O13120.5 (3)C10—N2—C6118.5 (3)
O14—C11—C15119.1 (3)C10—N2—Cu1126.8 (2)
O13—C11—C15120.4 (3)C6—N2—Cu1114.8 (2)
O14—C11—Cu1ii58.05 (16)C23—N3—C19119.2 (3)
O13—C11—Cu1ii62.60 (17)C23—N3—Cu2115.6 (2)
C15—C11—Cu1ii174.8 (2)C19—N3—Cu2124.6 (2)
O11—C12—O10124.3 (3)C28—N4—C24119.1 (3)
O11—C12—C13118.5 (3)C28—N4—Cu2126.4 (2)
O10—C12—C13117.1 (3)C24—N4—Cu2114.5 (2)
C18—C13—C14119.6 (3)O6—N5—O7123.5 (3)
C18—C13—C12121.0 (3)O6—N5—C34118.3 (3)
C14—C13—C12119.4 (3)O7—N5—C34118.2 (3)
C13—C14—C15121.0 (3)O9—N6—O8123.4 (3)
C13—C14—H14119.5O9—N6—C17119.1 (3)
C15—C14—H14119.5O8—N6—C17117.6 (4)
C16—C15—C14119.8 (3)Cu2—O1—H3W118 (3)
C16—C15—C11120.1 (3)Cu2—O1—H4W112 (3)
C14—C15—C11120.0 (3)H3W—O1—H4W113 (4)
C15—C16—C17117.8 (3)C29—O2—Cu2122.8 (2)
C15—C16—H16121.1C36—O4—Cu2i93.58 (18)
C17—C16—H16121.1C36—O5—Cu2i86.30 (19)
C16—C17—C18123.9 (3)C12—O10—Cu1121.3 (2)
C16—C17—N6118.4 (3)Cu1—O12—H1W106 (3)
C18—C17—N6117.6 (3)Cu1—O12—H2W121 (3)
C13—C18—C17117.9 (3)H1W—O12—H2W112 (4)
C13—C18—H18121.0C11—O13—Cu1ii87.6 (2)
C17—C18—H18121.0C11—O14—Cu1ii92.45 (19)
Symmetry codes: (i) x+1, y, z; (ii) x−1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O12—H1W···O2i0.83 (4)1.98 (2)2.742 (3)153 (4)
O1—H4W···O10ii0.82 (3)1.95 (2)2.724 (3)158 (4)
O12—H2W···O50.82 (4)2.07 (3)2.760 (3)141 (4)
O1—H3W···O130.83 (3)2.13 (3)2.778 (3)135 (4)
Symmetry codes: (i) x+1, y, z; (ii) x−1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O12—H1W···O2i0.83 (4)1.98 (2)2.742 (3)153 (4)
O1—H4W···O10ii0.82 (3)1.95 (2)2.724 (3)158 (4)
O12—H2W···O50.82 (4)2.07 (3)2.760 (3)141 (4)
O1—H3W···O130.83 (3)2.13 (3)2.778 (3)135 (4)
Symmetry codes: (i) x+1, y, z; (ii) x−1, y, z.
Acknowledgements top

This work was supported by the Natural Science Foundation of Shandong Province (grant No. Y2007D39).

references
References top

Bruker (2001). SAINT-Plus. Bruker AXS Inc., Madison, Wisconsin, USA.

Bruker (2004). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.

Church, B. S. & Halvorson, H. (1959). Nature (London), 183, 124–125.

Kim, Y., Lee, E. & Jung, D. Y. (2001). Chem. Mater. 13, 2684–2690.

Okabe, N. & Oya, N. (2000). Acta Cryst. C56, 1416–1417.

Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122.