Acta Cryst. (2008). E64, m1516  [ doi:10.1107/S1600536808033692 ]

Bis(ethylenedithio)tetrathiafulvalenium-tetrachloridocobaltate(II) (3/2)

F. Zhao, P. Li, X. Zhu and L. Dong

Abstract: The structure of the electrochemically crystallized title compound, (C₁₀H₈S₈)₃[CoCl₄]₂, consists of two types of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetrahedral [CoCl₄]^2- anions. One of the BEDT-TTF molecules is generated by inversion. There are short SS contacts between the stacks in the a direction and short C-HCl contacts between the radical cations and the anions.

Online 8 November 2008

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