Acta Cryst. (2008). E64, m1513  [ doi:10.1107/S160053680803585X ]

[-2,2,4,4,6,6-Hexakis(3,5-dimethylpyrazol-1-yl)-2⁵,4⁵,6⁵-1,3,5,2,4,6-triazatriphosphinine]bis[bis(nitrato- ²O,O')cadmium(II)]

S. Y. Yun and S. W. Lee

Abstract: The complete title complex, [Cd₂(NO₃)₄(C₃₀H₄₂N₁₅P₃)], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclotriphosphazene ligand located on the rotation axis. The non-planar cyclotriphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclotriphosphazene N atom.

Online 8 November 2008

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