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Acta Cryst. (2008). E64, m1599  [ doi:10.1107/S1600536808038385 ]

Poly[di-[mu]3-chlorido-[[mu]2-(3-pyridyl)(4-pyridyl)methanone-[kappa]2N:N']dicopper(I)]

J. L. Hittle and R. L. LaDuca

Abstract: In the title compound, [Cu2Cl2(C11H8N2O)]n, stair-like ribbons of formula [Cu2Cl2]n are linked into coordination polymer layers by tethering (3-pyridyl)(4-pyridyl)methanone (3,4'-dpk) ligands. The two distinct CuI centres both adopt distorted CuNCl3 tetrahedral coordinations. Individual [Cu2Cl2(3,4'-dpk)]n layers stack in an AB pattern along the c direction by way of weak C-H...O interactions between the pyridyl rings and ketone O atoms.


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