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Acta Cryst. (2008). E64, m1615  [ doi:10.1107/S1600536808038580 ]

Bis[benzyl N'-(1H-indol-3-ylmethylene)hydrazinecarbodithioato-[kappa]2N',S]nickel(II) N,N-dimethylformamide disolvate

H. Khaledi, H. Mohd Ali and S. W. Ng

Abstract: In the title compound, [Ni(C17H14N3S2)2]·2C3H7NO, the Ni atom (site symmetry \overline{1}) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N-H...O hydrogen bond links the complex to the dimethylformamide solvent molecule.


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