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Acta Cryst. (2008). E64, m1583-m1584  [ doi:10.1107/S1600536808038129 ]

Dibromido(di-2-pyridylamine-[kappa]2N,N')mercury(II)

K. Kalateh, A. Norouzi, A. Ebadi, R. Ahmadi and V. Amani

Abstract: In the molecule of the title compound, [HgBr2(C10H9N3)], the HgII atom is four-coordinated in a distorted tetrahedral configuration by two N atoms from the chelating di-2-pyridylamine ligand and by two Br atoms. In the crystal structure, intermolecular N-H...Br hydrogen bonds link the molecules into centrosymmetric dimers. There are [pi]-[pi] contacts between the pyridine rings [centroid-centroid distances = 3.9662 (5) and 3.9321 (4) Å]. There also exists a C-H...[pi] contact between the pyridine CH group and a pyridine ring.

Online 20 November 2008


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