Acta Cryst. (2008). E64, m1503  [ doi:10.1107/S1600536808033783 ]

Bis(5-bromopyridine-2-carboxylato-O)triphenylantimony(V)

L. Quan, H. Yin and D. Wang

Abstract: In the title compound, [Sb(C₆H₅)₃(C₆H₃BrNO₂)₂], the Sb center has a distorted trigonal-bipyramidal geometry, with two carboxylate O atoms of two 5-bromopyridine-2-carboxylate ligands in equatorial positions and three phenyl ligands in axial positions. The crystal structure is stabilized by C-HBr hydrogen bonds and intermolecular C-Br interactions [C = 3.57 (1) Å].

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