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Acta Cryst. (2008). E64, m1519-m1520 [ doi:10.1107/S1600536808036167 ]
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2-2-aminoethanethiolato)triiron(III) tris(perchlorate)Abstract: In the title salt, [Fe3(C2H6NS)6](ClO4)3, the trinuclear cation lies on a special position of 
site symmetry; the central Fe atom is coordinated by six thiolate groups from the two flanking fac-(S)-[Fe(C2H6NS)3] units. In the flanking units, the three C2H6NS groups each chelate to the metal atom. The cations interact with the perchlorate anions through weak N-H
O hydrogen bonds resulting in a three-dimensional network. In the asymmetric unit two cations are present, one of which is disordered over two positions with occupancies of 0.75 and 0.25.
Online 8 November 2008
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