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Acta Cryst. (2008). E64, m1582  [ doi:10.1107/S1600536808038257 ]

[O-Ethyl N-(4-nitrophenyl)thiocarbamato-[kappa]S](tri-p-tolylphosphine-[kappa]P)gold(I)

G. A. Broker and E. R. T. Tiekink

Abstract: A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...[pi] contact [Au...Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].

Online 20 November 2008


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