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Acta Cryst. (2008). E64, m1587  [ doi:10.1107/S160053680803804X ]

catena-Poly[[bis([mu]2-4-aminobenzenesulfonato-[kappa]2O:O)disilver]-bis([mu]2-4,4'-bipyridine-[kappa]2N:N')]

G.-C. Ou, M. Zhang, X.-Y. Yuan and Y.-Q. Dai

Abstract: In the title compound, [Ag2(C6H6NO3S)2(C10H8N2)2]n, the AgI atom is four-coordinated by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) and two O atoms from two independent 4-aminobenzenesulfonate (ABS) ligands. The two inter-chain AgI atoms are bridged by two independent ABS ligands through weak Ag-O bonds and Ag...Ag attractions, forming a ladder-like chain coordination polymer [Ag2(ABS)2(bipy)2]n parallel to [001], which is further linked to generate a two-dimensional structure via N-H...O hydrogen-bonding interactions.

Online 22 November 2008


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