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Acta Cryst. (2008). E64, m1506  [ doi:10.1107/S1600536808035551 ]

[[mu]-10,21-Dimethyl-3,6,14,17-tetrazatricyclo[17.3.1.18,12]tetracosa-1(23),2,6,8,10,12 (24),13,17,19,21-decaene-23,24-diolato-[kappa]4N3,N6,O23,O24:[kappa]4N14,N17,O23,O24]bis(perchlorato-[kappa]O)dimanganese(II)

J. Liu, Z.-Q. Pan, H. Zhou and Y.-Z. Li

Abstract: In the centrosymmetric and dinuclear title complex, [Mn2(C22H22N4O2)(ClO4)2], the two Mn atoms are bridged by two phenolate O atoms of the N4O2 macrocycle with an Mn...Mn distance of 2.9228 (11) Å. The distorted square-pyramidal N2O3 coordination geometry is completed by an O atom derived from a perchlorate anion.

Online 8 November 2008


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