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Acta Cryst. (2009). E65, m99 [ doi:10.1107/S1600536808042335 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-Oxido-bis[(2-chloronicotinato-![[kappa]](/logos/entities/kappa_rmgif.gif)
O)triphenylantimony(V)]Abstract: A new dinuclear triphenylantimony(V) derivative with an oxide bridge, [Sb2(C6H5)6(C6H3ClNO2)2O], has been synthesized. Each Sb atom is five-coordianted by three C atoms and two O atoms in a distorted trigonal-bipyramidal geometry. Metal centers are bridged by a 2-oxide functionality, and phenyl substituents on Sb atoms are in an staggered arrangement. The Sb-O-Sb bridge displays a bent geometry with an angle of 165.1 (4)°. Molecules interact in the crystal through weak C-H
O and C-HN intermolecular hydrogen bonds.
Online 20 December 2008
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