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Acta Cryst. (2009). E65, o24  [ doi:10.1107/S1600536808039214 ]

N-(3-Bromo-1,4-dioxo-1,4-dihydro-2-naphthyl)-2-chloro-N-(2-chlorobenzoyl)benzamide

E. S. Akinboye, R. J. Butcher, Y. Brandy, T. A. Adesiyun and O. Bakare

Abstract: The title compound, C24H12BrCl2NO4, was synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 2-chlorobenzoyl chloride. The crystal structure shows that each of the chlorophenyl rings is inclined at about 60° to the naphthoquinone ring system. The two chlorophenyl rings adopt a conformation that ensures that chlorine substituents are anti so as to reduce electronic repulsion. An examination of the packing shows close O...Br and Cl...Cl contacts of 2.947 (2) and 3.346 (1) Å, respectively. In addition, the molecules are linked by weak intermolecular C-H...O and C-H...Cl interactions.

Online 6 December 2008


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