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Acta Cryst. (2009). E65, m4-m5  [ doi:10.1107/S1600536808039913 ]

Bis([mu]-3-carboxy-2-oxidobenzoato)-[kappa]3O1,O2:O3;[kappa]3O3:O1,O2-bis[aqua(2,2'-bipyridine-[kappa]2N,N')copper(II)]

J. Gao, B.-Y. Zhu and D.-L. Cui

Abstract: In the centrosymmetric dinuclear complex, [Cu2(C8H4O5)2(C10H8N2)2(H2O)2], the CuII ion is coordinated by two N atoms from a bipyridine ligand, three O atoms from two 3-carboxy-2-oxidobenzoate dianions and the O atom of the water molecule in a distorted octahedral geometry. The Cu--O(H) coordination [2.931 (3) Å] is very weak. In the crystal structure, the dinuclear units are linked into a two-dimensional network parallel to (010) by O-H...O hydrogen bonds.

Online 3 December 2008


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