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Acta Cryst. (2009). E65, o62-o63  [ doi:10.1107/S1600536808041020 ]

(Z)-Methyl 4-({3-[(2,5-dioxoimidazolidin-4-ylidene)methyl]-1H-indol-1-yl}methyl)benzoate

N. R. Penthala, T. R. Y. Reddy, S. Parkin and P. A. Crooks

Abstract: In the title compound, C21H17N3O4, pairs of molecules form a planar[maximum deviation 0.0566 (9) Å] centrosymmetric imidazole dimer via two N-H...O hydrogen bonds. These dimeric units are linked by further N-H...O hydrogen bonds between the ester carbonyl group and the imidazolidine ring, formiing chains parallel to the c-axis direction. In addition, there are [pi]-[pi] stacking interactions between the planar imidazole pairs, with an interplanar spacing of 3.301 (2) Å. There is a double bond with Z geometry connecting the imidazolidine and indole units.

Online 10 December 2008


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