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Acta Cryst. (2009). E65, m7  [ doi:10.1107/S1600536808036593 ]

Tris(2,2'-bipyridine-[kappa]2N,N')cadmium(II) bis(perchlorate) hemihydrate

W. Zhang, Z. Jiang and L. Lu

Abstract: The asymmetric unit of the title compound, [Cd(C10H8N2)3](ClO4)2·0.5H2O, consists of one complex [Cd(bpy)3]2+ cation (bpy = 2,2'-bipyridine), two perchlorate anions and one water molecule with half-occupancy. The central cadmium(II) ion is bound to six N atoms from three bpy ligands in a distorted octahedral coordination, with Cd-N bond distances ranging from 2.304 (3) to 2.395 (2) Å.

Online 3 December 2008


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