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Acta Cryst. (2009). E65, m122  [ doi:10.1107/S1600536808042992 ]

Poly[([mu]-4,4'-bipyridine)([mu]-naphthalene-1,4-dicarboxylato)iron(II)]

J. Boeckmann, I. Jess and C. Näther

Abstract: The asymmetric unit of the title compound, [Fe(C12H6O4)(C10H8N2)], consists of two independent Fe(II) atoms, two naphthalene-1,4-dicarboxylate anions and two 4,4'-bipyridine ligands. The Fe(II) atoms are each coordinated by four O atoms of the naphthalene-1,4-dicarboxylate anions and two N atoms of the 4,4'-bipyridine ligands within a distorted octahedron. Two Fe(II) atoms are bridged via the carboxylate groups of two symmetry-related anions into dimers, which are further connected into chains. These chains are linked by additional anions into layers that are finally connected by the 4,4'-bipyridine ligands into a three-dimensional coordination network.

Online 20 December 2008


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