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Acta Cryst. (2009). E65, m66-m67  [ doi:10.1107/S1600536808041779 ]

Poly[([mu]-5,7-dihydroxy-4-oxo-2-phenyl-4H-chromene-8-sulfonato)potassium(I)]

B. Liu and B.-L. Yang

Abstract: In the polymeric title compound, [K(C15H9O7S)]n, the potassium cation is five-coordinated by four sulfonate O atoms and one carbonyl O atom. Two intramolecular O-H...O hydrogen bonds stabilize the conformation of the anion. The polymeric three-dimensional supramolecular architecture is formed via coordination interactions and [pi]-[pi] stacking interactions involving centrosymmetrically related pyrone rings, with a centroid-centroid separation of 3.513 (2) Å.

Online 13 December 2008


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