Acta Cryst. (2009). E65, m61-m62  [ doi:10.1107/S160053680804169X ]

(4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-³O²,N¹,S)(1,10-phenanthroline-²N,N')zinc(II) dimethyl sulfoxide disolvate monohydrate

K. W. Tan, C. H. Ng, M. J. Maah and S. W. Ng

Abstract: The Zn^II atom in the title compound, [Zn(C₈H₇N₃O₂S)(C₁₂H₈N₂)]·2C₂H₆OS·H₂O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

Online 13 December 2008

Copyright © International Union of Crystallography
IUCr Webmaster